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This paper presents the development of a potential fault diagnosis system of power transformers by an artificial neural network (ANN) based on the gas components of dissolved gas-in-oil analysis (DGA) data. The input of the ANN is five components H2, C2H4, CH4, C2H2, C2H6. The outputs are 3 major conclusions about the condition of the transformer including “normal”, “overheating” and “discharging”. Using Multi-Layer Perception network (MLP) with a selected network structure of 5-16-3. Through testing with actual DGA data, the results show that the diagnostic system makes conclusions that are reliable